Abstract
Triphenylphosphine inserts into the peroxide bond of 1,2-dioxines, initiating ring contraction with loss of triphenylphosphine oxide. This process yields dihydrofuran oxides in 54-97% yield from oxirenyl[2,3-c][1,2]dioxines and dihydrofurans from 3,6-dihydro-1,2-dioxines with inversion of stereochemistry at either the 2 or 5 position in the furan product.
| Original language | English |
|---|---|
| Pages (from-to) | 2577-2579 |
| Journal | The Journal of Organic Chemistry |
| Volume | 69 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 2004 |
Keywords
- Organic Chemical Synthesis
- Organic Chemistry
Fingerprint
Dive into the research topics of 'Triphenylphosphine-Induced Ring Contraction of 1,2-Dioxines'. Together they form a unique fingerprint.Cite this
- APA
- Author
- BIBTEX
- Harvard
- Standard
- RIS
- Vancouver