Rayleigh Depolarization Ratios, Kerr Effects, Polarizabilities, and Hyperpolarizabilities of CH₃Br, CH₂Br₂, CHBr₃ and CBr₄.: Comparison of Experimental and ab Initio Calculated Polarizabilities

Ewan Blanch; Roland Keir; Geoffrey Ritchie

doi:10.1021/jp020003t

Rayleigh Depolarization Ratios, Kerr Effects, Polarizabilities, and Hyperpolarizabilities of CH₃Br, CH₂Br₂, CHBr₃ and CBr₄. Comparison of Experimental and ab Initio Calculated Polarizabilities

Ewan Blanch, Roland Keir, Geoffrey Ritchie

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Improved equipment has been used to record the vapor-phase Rayleigh depolarization ratios and electrooptical Kerr effects of CH₃Br, CH₂Br₂, CHBr₃, and CBr₄ at elevated temperatures. The measurements yield experimental values of the anisotropic polarizabilities and the Kerr hyperpolarizabilities of these molecules. As well, Dougherty and Spackman's HUZ-SV(+sd+sp) basis set has been used to compute SCF and MP2-level polarizabilities, and these are compared with the experimental results.

Original language	English
Pages (from-to)	4257-4262
Journal	The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
Volume	106
Issue number	16
DOIs	https://doi.org/10.1021/jp020003t
Publication status	Published - 2002

Keywords

Atomic and Molecular Physics

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10.1021/jp020003t

https://hdl.handle.net/1959.11/1435

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Cite this

Blanch, E., Keir, R., & Ritchie, G. (2002). Rayleigh Depolarization Ratios, Kerr Effects, Polarizabilities, and Hyperpolarizabilities of CH₃Br, CH₂Br₂, CHBr₃ and CBr₄. Comparison of Experimental and ab Initio Calculated Polarizabilities. The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory, 106(16), 4257-4262. https://doi.org/10.1021/jp020003t

Blanch, Ewan ; Keir, Roland ; Ritchie, Geoffrey. / Rayleigh Depolarization Ratios, Kerr Effects, Polarizabilities, and Hyperpolarizabilities of CH₃Br, CH₂Br₂, CHBr₃ and CBr₄. Comparison of Experimental and ab Initio Calculated Polarizabilities. In: The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory. 2002 ; Vol. 106, No. 16. pp. 4257-4262.

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abstract = "Improved equipment has been used to record the vapor-phase Rayleigh depolarization ratios and electrooptical Kerr effects of CH₃Br, CH₂Br₂, CHBr₃, and CBr₄ at elevated temperatures. The measurements yield experimental values of the anisotropic polarizabilities and the Kerr hyperpolarizabilities of these molecules. As well, Dougherty and Spackman's HUZ-SV(+sd+sp) basis set has been used to compute SCF and MP2-level polarizabilities, and these are compared with the experimental results.",

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Blanch, E, Keir, R & Ritchie, G 2002, 'Rayleigh Depolarization Ratios, Kerr Effects, Polarizabilities, and Hyperpolarizabilities of CH₃Br, CH₂Br₂, CHBr₃ and CBr₄. Comparison of Experimental and ab Initio Calculated Polarizabilities', The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory, vol. 106, no. 16, pp. 4257-4262. https://doi.org/10.1021/jp020003t

Rayleigh Depolarization Ratios, Kerr Effects, Polarizabilities, and Hyperpolarizabilities of CH₃Br, CH₂Br₂, CHBr₃ and CBr₄. Comparison of Experimental and ab Initio Calculated Polarizabilities. / Blanch, Ewan; Keir, Roland; Ritchie, Geoffrey.
In: The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory, Vol. 106, No. 16, 2002, p. 4257-4262.

Research output: Contribution to journal › Article › peer-review

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T1 - Rayleigh Depolarization Ratios, Kerr Effects, Polarizabilities, and Hyperpolarizabilities of CH₃Br, CH₂Br₂, CHBr₃ and CBr₄.

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AU - Keir, Roland

AU - Ritchie, Geoffrey

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AB - Improved equipment has been used to record the vapor-phase Rayleigh depolarization ratios and electrooptical Kerr effects of CH₃Br, CH₂Br₂, CHBr₃, and CBr₄ at elevated temperatures. The measurements yield experimental values of the anisotropic polarizabilities and the Kerr hyperpolarizabilities of these molecules. As well, Dougherty and Spackman's HUZ-SV(+sd+sp) basis set has been used to compute SCF and MP2-level polarizabilities, and these are compared with the experimental results.

KW - Atomic and Molecular Physics

UR - https://www.scopus.com/pages/publications/0037172158

U2 - 10.1021/jp020003t

DO - 10.1021/jp020003t

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JO - The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

JF - The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

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ER -