Rapid and Systematic Access to Quasi-Diblock Copolymer Libraries Covering a Comprehensive Composition Range by Sequential RAFT Polymerization in an Automated Synthesizer

Joris J Haven; Carlos Guerrero-Sanchez; Daniel Keddie; Graeme Moad

doi:10.1002/marc.201300459

Rapid and Systematic Access to Quasi-Diblock Copolymer Libraries Covering a Comprehensive Composition Range by Sequential RAFT Polymerization in an Automated Synthesizer

Joris J Haven, Carlos Guerrero-Sanchez, Daniel Keddie, Graeme Moad

School of Science & Technology

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries via sequential RAFT polymerization in an automated synthesizer is reported. The procedure is demonstrated with the synthesis of a 23 member library of low dispersity poly(butyl methacrylate)-quasiblock-poly(methyl methacrylate) covering a wide (fivefold) range of molar mass for the second block in a one-pot, sequential, RAFT polymerization.

Original language	English
Pages (from-to)	492-497
Journal	Macromolecular Rapid Communications
Volume	35
Issue number	4
DOIs	https://doi.org/10.1002/marc.201300459
Publication status	Published - 2014

Keywords

Synthesis of Materials
Polymerisation Mechanisms

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10.1002/marc.201300459

https://hdl.handle.net/1959.11/15375

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abstract = "A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries via sequential RAFT polymerization in an automated synthesizer is reported. The procedure is demonstrated with the synthesis of a 23 member library of low dispersity poly(butyl methacrylate)-quasiblock-poly(methyl methacrylate) covering a wide (fivefold) range of molar mass for the second block in a one-pot, sequential, RAFT polymerization.",

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Rapid and Systematic Access to Quasi-Diblock Copolymer Libraries Covering a Comprehensive Composition Range by Sequential RAFT Polymerization in an Automated Synthesizer. / Haven, Joris J; Guerrero-Sanchez, Carlos; Keddie, Daniel et al.
In: Macromolecular Rapid Communications, Vol. 35, No. 4, 2014, p. 492-497.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Rapid and Systematic Access to Quasi-Diblock Copolymer Libraries Covering a Comprehensive Composition Range by Sequential RAFT Polymerization in an Automated Synthesizer

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AU - Guerrero-Sanchez, Carlos

AU - Keddie, Daniel

AU - Moad, Graeme

PY - 2014

Y1 - 2014

N2 - A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries via sequential RAFT polymerization in an automated synthesizer is reported. The procedure is demonstrated with the synthesis of a 23 member library of low dispersity poly(butyl methacrylate)-quasiblock-poly(methyl methacrylate) covering a wide (fivefold) range of molar mass for the second block in a one-pot, sequential, RAFT polymerization.

AB - A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries via sequential RAFT polymerization in an automated synthesizer is reported. The procedure is demonstrated with the synthesis of a 23 member library of low dispersity poly(butyl methacrylate)-quasiblock-poly(methyl methacrylate) covering a wide (fivefold) range of molar mass for the second block in a one-pot, sequential, RAFT polymerization.

KW - Synthesis of Materials

KW - Polymerisation Mechanisms

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DO - 10.1002/marc.201300459

M3 - Article

SN - 1022-1336

VL - 35

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JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 4

ER -

Rapid and Systematic Access to Quasi-Diblock Copolymer Libraries Covering a Comprehensive Composition Range by Sequential RAFT Polymerization in an Automated Synthesizer

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