[N,N'-bis-(o-sulfidobenzylidene)-1,3-diaminopropane]nickel(II) 1,4-dioxane solvate

Michelle K Taylor; John Reglinski; Dawn Wallace

doi:10.1107/S1600536804011882

[N,N'-bis-(o-sulfidobenzylidene)-1,3-diaminopropane]nickel(II) 1,4-dioxane solvate

Michelle K Taylor, John Reglinski, Dawn Wallace

Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title tetradentate Schiff base complex (systematic name: {2,2'-[propane-1,3-diylbis(nitrilomethylidyne)]benzenethiolato- κ⁴S,N,N',S'}nickel(II) 1,4-dioxane solvate), [Ni(C₁₇H₁₆-N₂S₂)]·C₄H₈O₂, contains an Ni atom coordinated within a tetrahedrally distorted planar N₂S₂ environment, with average Ni-N and N-S bond lengths of 1.922 (1) and 2.167 (1) Å, respectively.

Original language	English
Pages (from-to)	m850-m851
Journal	Acta crystallographica. Section E
Volume	60
Issue number	6
DOIs	https://doi.org/10.1107/S1600536804011882
Publication status	Published - 2004

Keywords

Structural Chemistry and Spectroscopy
Transition Metal Chemistry

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@article{bf7dce480348417e8329825132d29040,

title = "[N,N'-bis-(o-sulfidobenzylidene)-1,3-diaminopropane]nickel(II) 1,4-dioxane solvate",

abstract = "The title tetradentate Schiff base complex (systematic name: \{2,2'-[propane-1,3-diylbis(nitrilomethylidyne)]benzenethiolato- κ⁴S,N,N',S'\}nickel(II) 1,4-dioxane solvate), [Ni(C₁₇H₁₆-N₂S₂)]·C₄H₈O₂, contains an Ni atom coordinated within a tetrahedrally distorted planar N₂S₂ environment, with average Ni-N and N-S bond lengths of 1.922 (1) and 2.167 (1) {\AA}, respectively.",

keywords = "Structural Chemistry and Spectroscopy, Transition Metal Chemistry",

author = "Taylor, \{Michelle K\} and John Reglinski and Dawn Wallace",

year = "2004",

doi = "10.1107/S1600536804011882",

language = "English",

volume = "60",

pages = "m850--m851",

journal = "Acta crystallographica. Section E",

issn = "1600-5368",

publisher = "International Union of Crystallography (IUCr)",

number = "6",

}

TY - JOUR

T1 - [N,N'-bis-(o-sulfidobenzylidene)-1,3-diaminopropane]nickel(II) 1,4-dioxane solvate

AU - Taylor, Michelle K

AU - Reglinski, John

AU - Wallace, Dawn

PY - 2004

Y1 - 2004

N2 - The title tetradentate Schiff base complex (systematic name: {2,2'-[propane-1,3-diylbis(nitrilomethylidyne)]benzenethiolato- κ⁴S,N,N',S'}nickel(II) 1,4-dioxane solvate), [Ni(C₁₇H₁₆-N₂S₂)]·C₄H₈O₂, contains an Ni atom coordinated within a tetrahedrally distorted planar N₂S₂ environment, with average Ni-N and N-S bond lengths of 1.922 (1) and 2.167 (1) Å, respectively.

AB - The title tetradentate Schiff base complex (systematic name: {2,2'-[propane-1,3-diylbis(nitrilomethylidyne)]benzenethiolato- κ⁴S,N,N',S'}nickel(II) 1,4-dioxane solvate), [Ni(C₁₇H₁₆-N₂S₂)]·C₄H₈O₂, contains an Ni atom coordinated within a tetrahedrally distorted planar N₂S₂ environment, with average Ni-N and N-S bond lengths of 1.922 (1) and 2.167 (1) Å, respectively.

KW - Structural Chemistry and Spectroscopy

KW - Transition Metal Chemistry

UR - https://www.scopus.com/pages/publications/8844262651

U2 - 10.1107/S1600536804011882

DO - 10.1107/S1600536804011882

M3 - Article

SN - 1600-5368

VL - 60

SP - m850-m851

JO - Acta crystallographica. Section E

JF - Acta crystallographica. Section E

IS - 6

ER -

[N,N'-bis-(o-sulfidobenzylidene)-1,3-diaminopropane]nickel(II) 1,4-dioxane solvate

Abstract

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