Highly-oxidised, sulfur-rich, mixed-valence vanadium(IV/V) complexes

Michelle K Taylor; DJ Evans; CG Young

doi:10.1039/B610036H

Highly-oxidised, sulfur-rich, mixed-valence vanadium(IV/V) complexes

Michelle K Taylor
, DJ Evans
, CG Young

Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The reactions of [V₂(μ-S₂)₂(S₂CNR₂)₄] (R = alkyl) with NOBF₄ produce highly-oxidised, sulfur-rich, V(IV/V) complexes, [V2(μ-S₂)₂(S₂CNR₂)₄]BF₄, that exhibit 15-line EPR spectra and structures consistent with Class III mixed-valence behaviour.

Original language	English
Pages (from-to)	4245-4246
Journal	Chemical Communications
Issue number	40
DOIs	https://doi.org/10.1039/B610036H
Publication status	Published - 2006

Keywords

Transition Metal Chemistry

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10.1039/B610036H

https://hdl.handle.net/1959.11/8274

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@article{274df896bac540dea0a9ffe27049f782,

title = "Highly-oxidised, sulfur-rich, mixed-valence vanadium(IV/V) complexes",

abstract = "The reactions of [V₂(μ-S₂)₂(S₂CNR₂)₄] (R = alkyl) with NOBF₄ produce highly-oxidised, sulfur-rich, V(IV/V) complexes, [V2(μ-S₂)₂(S₂CNR₂)₄]BF₄, that exhibit 15-line EPR spectra and structures consistent with Class III mixed-valence behaviour.",

keywords = "Transition Metal Chemistry",

author = "Taylor, \{Michelle K\} and DJ Evans and CG Young",

year = "2006",

doi = "10.1039/B610036H",

language = "English",

pages = "4245--4246",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "40",

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TY - JOUR

T1 - Highly-oxidised, sulfur-rich, mixed-valence vanadium(IV/V) complexes

AU - Taylor, Michelle K

AU - Evans, DJ

AU - Young, CG

PY - 2006

Y1 - 2006

N2 - The reactions of [V₂(μ-S₂)₂(S₂CNR₂)₄] (R = alkyl) with NOBF₄ produce highly-oxidised, sulfur-rich, V(IV/V) complexes, [V2(μ-S₂)₂(S₂CNR₂)₄]BF₄, that exhibit 15-line EPR spectra and structures consistent with Class III mixed-valence behaviour.

AB - The reactions of [V₂(μ-S₂)₂(S₂CNR₂)₄] (R = alkyl) with NOBF₄ produce highly-oxidised, sulfur-rich, V(IV/V) complexes, [V2(μ-S₂)₂(S₂CNR₂)₄]BF₄, that exhibit 15-line EPR spectra and structures consistent with Class III mixed-valence behaviour.

KW - Transition Metal Chemistry

U2 - 10.1039/B610036H

DO - 10.1039/B610036H

M3 - Article

SN - 1359-7345

SP - 4245

EP - 4246

JO - Chemical Communications

JF - Chemical Communications

IS - 40

ER -

Highly-oxidised, sulfur-rich, mixed-valence vanadium(IV/V) complexes

Abstract

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