Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3)4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials

Siew Huay Chong; Antonius Tjindrawan; T S Andy Hor

doi:10.1016/s1381-1169(03)00308-x

Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3)4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials

Siew Huay Chong
, Antonius Tjindrawan
, T S Andy Hor

Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Activity of [Pt₂(μ-S)₂(PPh₃)₄] (1) towards 1,4-dichlorobutane, 1,2-dichloroethane, α-α′-dichloro-o-xylene and α-α′-dichloro-m-xylene and the catalytic role of 1 in the syntheses of organosulfur materials was studied by in situ electrospray mass spectroscopy (ESMS). An intermediate, [Pt₂(μ-SC₂H₄S)(PPh₃)₄][PF₆]₂ (6) was isolated and characterized by single-crystal X-ray crystallographic diffractometry. In all reactions studied, the {Pt₂S₂} core is preserved, except for those involving excess NaBH₄. Treatment of 6 with excess NaBH₄ leads to the formation of mononuclear complex [Pt(η-S₂C₄H₈)(PPh₃)].

Original language	English
Pages (from-to)	267-277
Journal	Journal of Molecular Catalysis A: Chemical
Volume	204-205
DOIs	https://doi.org/10.1016/s1381-1169(03)00308-x
Publication status	Published - 15 Sept 2003

Access to Document

10.1016/s1381-1169(03)00308-x

https://hdl.handle.net/1959.11/74187

Handle.net

Persistent link

Fingerprint

Dive into the research topics of 'Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3)4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials'. Together they form a unique fingerprint.

Cite this

Chong, S. H., Tjindrawan, A., & Hor, T. S. A. (2003). Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3)4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials. Journal of Molecular Catalysis A: Chemical, 204-205, 267-277. https://doi.org/10.1016/s1381-1169(03)00308-x

@article{c5643217c3894b0e9a974a811f4c6cf3,

title = "Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3)4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials",

abstract = "Activity of [Pt2(μ-S)2(PPh3)4] (1) towards 1,4-dichlorobutane, 1,2-dichloroethane, α-α′-dichloro-o-xylene and α-α′-dichloro-m-xylene and the catalytic role of 1 in the syntheses of organosulfur materials was studied by in situ electrospray mass spectroscopy (ESMS). An intermediate, [Pt2(μ-SC2H4S)(PPh3)4][PF6]2 (6) was isolated and characterized by single-crystal X-ray crystallographic diffractometry. In all reactions studied, the \{Pt2S2\} core is preserved, except for those involving excess NaBH4. Treatment of 6 with excess NaBH4 leads to the formation of mononuclear complex [Pt(η-S2C4H8)(PPh3)].",

author = "Chong, \{Siew Huay\} and Antonius Tjindrawan and Hor, \{T S Andy\}",

year = "2003",

month = sep,

day = "15",

doi = "10.1016/s1381-1169(03)00308-x",

language = "English",

volume = "204-205",

pages = "267--277",

journal = "Journal of Molecular Catalysis A: Chemical",

issn = "1381-1169",

publisher = "Elsevier BV",

}

Chong, SH, Tjindrawan, A & Hor, TSA 2003, 'Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3)4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials', Journal of Molecular Catalysis A: Chemical, vol. 204-205, pp. 267-277. https://doi.org/10.1016/s1381-1169(03)00308-x

Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3)4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials. / Chong, Siew Huay; Tjindrawan, Antonius; Hor, T S Andy.
In: Journal of Molecular Catalysis A: Chemical, Vol. 204-205, 15.09.2003, p. 267-277.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3)4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials

AU - Chong, Siew Huay

AU - Tjindrawan, Antonius

AU - Hor, T S Andy

PY - 2003/9/15

Y1 - 2003/9/15

N2 - Activity of [Pt2(μ-S)2(PPh3)4] (1) towards 1,4-dichlorobutane, 1,2-dichloroethane, α-α′-dichloro-o-xylene and α-α′-dichloro-m-xylene and the catalytic role of 1 in the syntheses of organosulfur materials was studied by in situ electrospray mass spectroscopy (ESMS). An intermediate, [Pt2(μ-SC2H4S)(PPh3)4][PF6]2 (6) was isolated and characterized by single-crystal X-ray crystallographic diffractometry. In all reactions studied, the {Pt2S2} core is preserved, except for those involving excess NaBH4. Treatment of 6 with excess NaBH4 leads to the formation of mononuclear complex [Pt(η-S2C4H8)(PPh3)].

AB - Activity of [Pt2(μ-S)2(PPh3)4] (1) towards 1,4-dichlorobutane, 1,2-dichloroethane, α-α′-dichloro-o-xylene and α-α′-dichloro-m-xylene and the catalytic role of 1 in the syntheses of organosulfur materials was studied by in situ electrospray mass spectroscopy (ESMS). An intermediate, [Pt2(μ-SC2H4S)(PPh3)4][PF6]2 (6) was isolated and characterized by single-crystal X-ray crystallographic diffractometry. In all reactions studied, the {Pt2S2} core is preserved, except for those involving excess NaBH4. Treatment of 6 with excess NaBH4 leads to the formation of mononuclear complex [Pt(η-S2C4H8)(PPh3)].

U2 - 10.1016/s1381-1169(03)00308-x

DO - 10.1016/s1381-1169(03)00308-x

M3 - Article

SN - 1381-1169

VL - 204-205

SP - 267

EP - 277

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

ER -